In the present work we report on the study of local atomic and electronic structure of gold nanoparticles funnctionalised by thiol and amine containing long-chain ligands. The study of nanoscale atomic structure is performed by means of X-ray absorption spectroscopy (XANES: X-ray Absorption Near-Edge Structure) and computer simulation. In consequence of the experimantally obtained data analysis and computer simulation it was obtained that strong bonding takes place when 11-mercaptoundecanoic acid is bound to the gold nanoparticles surface, forming a chemical bond Au-S 0.25 nm in length. Weaker bonding is observed when forming bond between dodecylamine and gold nanoparticles surface atom resulting in Au-N bond 0.23 nm in length. Supplementary XANES spectra analysis by means of density functional theory reveals the nature of formation of the investigated nanoscale structure.

Keywords: nanoscale structure of matter, X-ray absorption spectroscopy, XANES, density functional theory, nanoparticles functionalisation

The problem of specificity of training students in high school artists. Defines the principles and features of training on the theoretical and practical sessions. Identifies the purposes of higher education.

Keywords: art education, teaching, vocational training, self-development

A widespread technology with deep litter floor with broilers. Promising material for bedding are the straw materials. However, straw, held a simple reduction, does not meet the zootechnical requirements, in particular the recommended length of the cut should be 50 mm to 150 mm. Thus, there arises the problem of fractionation straw, obtained at harvest crops as waste. We carried out an analysis of the different types of fractional chopped straw with nodal connections without them. Studies have been conducted on the behavior of these types in an air classifier with a velocity change .

Keywords: The straw residues fractionation aerodinomicheskie performance, fly speed

Tendencies of technological improvement of electronic chips led to reduction of their sizes, weight, development of functionality and decrease in power consumption. It allows us to discuss questions of developing renewable micro power sources which can provide power supply of autonomous microelectronic and micro circuitry systems for charge indication, paying attention to snow transfer, etc. 
The purpose of the paper is researching a profile of electrostatic field potential in the mountain district which was estimated as a possible use as a renewable micro power source.
It is found out that on windward sides of snow relieves the potential of electrostatic field exceeds three times to a similar  indicator for lee sides and is 80 V.  The potential is 3,5kV on polymeric surfaces (Nylon, teflon).   

Keywords: snow storming electricity, electrization, potential of electrostatic field, charge, the salting, the loaded particles of snow, innovation electronics, micro circuitry, renewable micro power sources.

The simulation of the process of the electrically active impurities relocation in the electric field of Schottky diode space charge region has been made. The analysis of the simulation results shows the possibility of controlled alloying impurities relocation on the depth about tens of nanometers caused by electrically active atoms diffusion in the electric field of Schottky diode space charge region.

Keywords: diffusion, space charge region, Schottky diode

The last ten years have seen a rapid growth of research related to the development of methods of localization of defects and assessment of technical condition of metal structures based on dynamic analysis. This paper presents the results of a study on the localization of defects arched steel truss. The main purpose of this article is to analyze the results of the damage index method and the development of the software module to localize structural damage. The results of numerical experiments presented in this article have shown the effectiveness of this method of localization of damage. The use of this method in practice will reduce the time of inspection by pre- defining a site design that are necessary to pay special attention during the field study.

Keywords: Vibration diagnostics, fault detection, diagnosis, construction construction spans, trusses, trusses, defect, damage, vibration, localization, identification

The solution of vibration problem for multilayered half plane with cavity of arbitrary shape is constructed using boundary element method. For the case of relatively much sunken cavity an asymptotic representations for fundamental solutions is used. The results of problem simulation for displacement and stress fields close to cavity surface are given using boundary element method

Keywords: multilayered environment, cavity of arbitrary shape, asymptotic analysis, boundary element method

To date, the main method of mass production of advanced functional materials for various purposes is the ceramic technology. In the manufacture of multi-component oxide compounds using of ceramic technology is difficult to achieve high uniformity of chemical composition. For activation of the raw ingredients and make it more uniform use of chemical-tions (co-precipitation of salts or hydroxides, spray drying, Cryochemistry) and physical-tions (mechano-chemical, microwave, ultrasonic) methods. The paper presents the results of work on obtaining Ni-Zn-ferrite 2000NN radiation-thermal sintering. The influence of base composition and alloying additions on the electromagnetic properties of the ferrites. Confirmed the effectiveness of the use of surface-active additives To increase the density of the raw pieces and level parameters. We propose a model that explain schaya efficiency of dopants in the radiation-thermal sintering.

Keywords: Nickel-zinc ferrite, radiation thermal sintering, base composition, alloying additives, permeability

The issue of increasing the strength of cutoff and grooving tools is considered in the paper. The principle of strength balance of edge is offered to be used in designing the replaceable inserts. The calculations are made and the shape is designed for the strength balanced front surface of the cutting tools. The analysis of the received data is made and the regularities of the designed shape of the front surface of the cutting edge are established. Designs of replaceable cutting inserts made with a glance to structural characteristics and operating conditions of the cutoff and grooving tools are offered.

Keywords: strength, cutting end, strength balance, cutting end, cutoff tools

The article describes directions optimization of supply chains of the consumer market, inventory management of wholesale and retail executives and organizations that make it up. Presented the study methods of inventory control, disclosed the problems of development of modern theoretical and methodological platform of inventory management in wholesale and retail networks.

Keywords: Inventory management, supply chain, wholesale and retail link, logistics optimization.

One of the main and most relevant and profitable areas of agricultural production - produce quality seeds in the farms, in the process of post-harvest grain processing. Was evaluated basic parameters of the separation process on the existing scheme sieve winnowing machine with certain technological characterization of the purified grain material according to the different conditions of separation, the possibility of defining a predetermined fraction of a feed and seed quality of purified material. Synthesis was performed variational various separation schemes and functioning to identify optimum operating parameters. According to the results of the experiment set technological possibility and the main characteristics of the process producing high-quality purified fraction of the material given by the scheme, which provides the best performance.

Keywords: grain material, fractionation, modeling, cleaning of grain

The problem of temperature stresses in revetments of concrete plates taking in the account various conditions of temperature impact is considered. Contact conditions for various friction coefficient are considered. The simulation is made using finite element method in Ansys © software. The examples of exact simulations for stress fields are given for different parameters of problem

Keywords: temperature stresses, concrete plate, finite element method

The intense strained state analysis results of the ""Kirovets"" KPP-16(20) portal crane trunk solid-state model are given in this work by a finite element method. Model operation of certainly element model in the program environment the Compass 3D v.14 is executed and results of its calculation in the form of the card of tension and the time-temperature chart for two cases of a loading are presented.

Keywords: finite element method, solid-state model, metal construction, portal crane, trunk, card of tension, time-temperature chart.

"This article is devoted to the development of the method for modeling elements of microsystems technology(MST) of membrane type. In this paper perforated membranes are considered and the impact of perforation on the mechanical properties of the membranes is examined. In numerical simulations of the elements it is proposed to use the equivalent mechanical parameters of perforated membranes obtained at the initial stage of the simulation. This will allow to obtain find the optimal parameters of perforation, reduce the time and resource modeling of MST elements. To test the technique numerical experiments were conducted for the two square membranes with sides 1.5 and 3 mm fixed on the contour of the same thickness. We studied the influence of the size of the perforation on the equivalent Young's modulus of the perforated membrane. "

Keywords: microsystems technology, numerical modeling, perforated membrane

The application of asymptotic analysis method for displacement fields in environment is considered on the basis of special representation of motion equation solutions for multilayered half plane in the case of steady vibrations. The large parameter in suggested research method is distance from force source to supposed view point with glance of wave re-reflection from layer boundaries. The results of numerical simulation is given and the conclusion about the effectiveness of suggested method for construction of asymptotic expansion is given.

Keywords: Asymptotic expansion, Fourier integral, multilayered environment