Fe-doped AlN nanorods were studied by means of x-ray absorption spectroscopy above the Fe K- and L2,3- edges. Theoretical simulations of the x-ray absorption spectra show that Fe atoms mainly substitute Al. A minor fraction of Fe interstitials or Fe-Al-N ternary alloy can be identified as well. Bader’s AIM analysis predicts that neutral substitutional FeAl defect is in 2+ charge state, though Al in pure AlN is in 3+ charge state. Fe L2,3 absorption spectra and photoluminescence data indicate the coexistence of Fe2+/Fe3+ in AlN:Fe nanorods so different charge states of substitutional FeAl should co-exist.
Keywords: diversification of management, production diversification, financial and economic purposes of a diversification, technological purposes of ensuring flexibility of production
This article reviews systems of respiratory activity registration in relation to sports medicine. Attention is devoted to the use of miniature accelerometers that record the movement of the chest, as the optimal method for the diagnosis of the respiratory parameters. Other methods are based on piezo-resistive sensors, pressure and airflow sensors, and airways resistance sensors. The authors' developed device based on three-axis accelerometer is proposed. It recognizes episodes of apnea with sufficient accuracy for long-term monitoring. The algorithm of the accelerometer data processing is described. In order to minimize noise impact on the useful signal it is necessary to transform the three-dimensional cloud of accelerometer data into a flat sector. Then the relation of gravity vector deviation angle and the nominal position in time is determined. This presented device due to its ability to transmit data via Bluetooth technology, after appropriate software development for mobile phone and the receiving terminal of medical professional, will be able to organize a simple ergonomic long-term remote monitoring of respiratory activity.
Keywords: systems of respiratory activity registration, long-term remote monitoring, three-axis accelerometer
The ability to choose the right anti-wear additives [1-6 ] allows you to create lubricants , which are thin layers have different properties than in large volumes. It is commonly assumed that the additives are functioning only in the zone boundary lubrication and are outside the scope of the hydrodynamic theory of lubrication . However, the beneficial effect of additives as indicated in many studies [1-5 ] we have in the " thin layer" of hydrodynamic lubrication .As is well known , lubrication bearings operate on different types of lubricants which are composed of base oil and additive compositions that provide the required functional properties of the oil . Additives polymers with high molecular weight oils impart viscoelastic properties . Analysis of existing studies [ 7-9] on the calculation of bearings running on a viscoelastic lubricant , shows that they do not take into account the dependence of the viscosity and shear modulus of the pressure and temperature, and mode of friction is assumed laminar. It is known [ 10 ] , high-speed bearings operating in turbulent friction , higher pressure and higher temperature, and so the development of methods for calculating the bearings running on a viscoelastic lubricant requires consideration of the above factors.In connection with the above written shall first develop the computational model of thrust bearings running on micropolar lubricant with the viscosity characteristics of the lubricant on the pressure in contrast to the existing theoretical models do not take into account these dependencies (task 1).And then consider the calculation model of extra load -bearing capacity , working on a viscoelastic lubricant for the dependence of its characteristics on the pressure (objective 2).
Keywords: thrust bearing with the abutment surface adapted, non-Newtonian lubricants
In this paper we study of the local atomic and electronic structure of nanostructured condensed material for rechargeable current sources on the basis of 15mas.%V2O5/Fe/LiF nanocomposite within charge-discharge cycle. Principle component analysis (PCA) of the series of Fe K-edge spectra collected during 1 st charge showing the concentrations of the components Fe, FeF2 and V[FeV]O4. We found the changes in the V oxidation state from the analysis of the experimental Fe K- and V K- XANES spectra. Total and partial density of states of components are presented.
Keywords: nanostructured materials for rechargeable current sources, dynamics of local atomic and electronic structures, XANES, DFT
The catalytic activity of Pt/C and PtxNi/C electrocatalysts prepared by borohydride methode was studed. It was established that the specific activity of fresh prepared Pt3,7Ni/C catalyst in oxygen electroreduction reaction is higher in compare with Pt/C material. After treatment of Pt3,7Ni/C material in the hot acid nickel in the surface layers of nanoparticles was dissolved and the composition of nanoparticles was changed to Pt5,6Ni. The electrochemical surface area of the Pt5,6Ni catalyst and specific activity was slightly decreased after corrosion treatment.
Keywords: platinum electrocatalysts, corrosion stability of the nanoparticles, fuel cells, X-ray diffraction, borohydride synthesis
The problems of building the architecture and design of the database structure for the storage of the structure of the chemical compounds and their analysis using heuristic algorithms
Proposed the structure of the database that allows you to store information about the structure of chemical compounds with varying degrees of detail. This approach simplifies forming of the structural descriptors used to build models of "structure-property" based on the genetic algorithms.
Keywords: database architecture, chemicals, data mining, heuristics
With the use of pulsed laser deposition and carbothermal synthesis а photosensitive structure on the basis of the Schottky barrier Au/ZnO(nanorods)/ZnO(film)/ZnO(nanorods)/Au was obtained. The parameters of the carbothermal method of synthesis of nanorods ZnO were optimized. Under directly applied bias of 7V current sensitivity of luminous flux for this photodetector is observed in the UV and visible regions of the spectrum, and is 0.14 A/W - for 325 nm and 0.18 A/W - to 405 nm, which means that this structure has the ability of potential applications in various fields for the control of UV radiation (for example, for the monitoring of solar UV radiation, control of UV radiation in air and disinfecting water devices).
Keywords: ZnO nanorods, Schottky barrier, photodetector, photosensitivity
ZnO nanorod arrays have been synthesized on silicon wafers by chemical vapor deposition (CVD) technique with different temperature modes, without metal catalyst. With this method vertically aligned ZnO nanostructures were grown at the quite low temperatures. Modification of the method allowed to place silicon substrates in areas with different ratios of concentrations of the molecules in the vapor phase. Photoluminescence spectroscopy and electron microscopy studies have shown that morphologies and optical properties of nanorods depends on different ratios of concentrations of the molecules in the vapor phase.
Keywords: ZnO nanorods,chemical vapor deposition (CVD), photoluminescence
The arrays of ZnO nanorods were obtained on the sapphire substrates by means of pulsed laser deposition under the high pressure of argon. The conditions of synthesis were optimized, and their influence on the morphology of ZnO nanostructures were revealed. It is shown that the concentration of oxygen vacancies in ZnO nanorods can be changed by regulation of the synthesis temperature from 850 to 915 °. This process can be controlled by the ratio of intensities of the photoluminescence emission in the visible and ultraviolet regions. So, it allows to create nanostructures for UV photodetectors or chemosensors depending on the temperature choice.
Keywords: ZnO nanorods, laser deposition, PLD, photoluminescence
In this paper the technology of repair of ground water retaining structures soil mixture improved quality with and without soil mixture install.Use soil mixture , improved sharps and ensure the return of ashes (repaired ) slopes and ridge structures of high strength (up to 13-15 MPa) and water resistance , thus increasing the effectiveness and quality of the repair work and increased resistance to the elements of the structures induced defect . The presence of the bran soil mixture not only enhances the strength of 30-40% , but also gives a significant increase in water and frost (20-30 %), which prevent or substantially reduce the infiltration of water through the filtration body water retaining structures , since high strength and frost soil-concrete being laid on a slope ( in the recovery slope failure ) and groove (at soil dumping and capacity to or in excess of the design marks ) will reliably protect the body of the dams ( dams ) of the drawdown , erosion , buckling , suffusion , and other deformities.
Keywords: technology, dribble feed , soil mixture, sift, cement, fly ash, dam, construction and repair operations, soil mixture installation, factors plan of the experiment, the regression equation
In the article authors examine specificities of internal components behavior changing in fiber-optical cable under influence of strong variable uniform electromagnetic field. There are some process variations proposed for describing of obtained results.
Keywords: fiber-optical cable, electrothermal degradation, kevlar, conductivity, open fiber-optical cable, partial discharges, water treeing
The article describes peculiarities of modern syntax parser systems and problems originating in text analysis. As a result of comparative analysis the authors propose a unified approach to processing of unstructured texts in Russian and English which combines morphology and syntax processing. The developed syntax analysis system, using verbs’ valency dictionary, samples of minimal structural schemes of sentences and samples of conjunctions, allows choosing predicative structures of sentences in the text, realizing initial semantic analysis due to semantic content of predicate’s actants and building trees of syntactical subordination of sentences. The derived trees hold elements of tree of constitutives and tree of dependences. The proposed samples and rules organization allows resolving some of the problems of modern parsers. And the use of verbs’ valency dictionary allows reducing the number of sentences syntax analysis variants.
Keywords: automatic text processing; syntax parser; morphological analysis; structural text elements
In this paper is offered hydraulic sensor to measure the kinematic, power and energy parameters. Developed scheme and the principles of the hydraulic sensor. Identification on the special flow lab with real modes of the device is determined by its performance in different conditions. Approximation of the results received dependences flow and pressure drop characteristics on the speed and entrance pressure, allowed more correctly assess and describe the operation of the hydraulic sensor over the entire range of speed and entrance pressure.
Keywords: hydraulic sensor, spilling method, flow and pressure drop characteristics, multifunction control unit.
An analysis of the problem of increasing the efficiency of the functioning of the logging trucks for hauling timber to the lower timber depots and consumers. Proposed technical solutions for of raising cross-trains in complex natural and industrial environments.
Keywords: Active semi-trailer used forestry, passableness, prosary operation.
The temperature dependencies of the main parameters of p-channel MOSFET model in a temperature range 20 ... 300 K are measured. The universal formal four-parametric model, which allows approximating all experimental temperature dependencies with the relative error less than 1 % is proposed. The model is intended for the MOSFETs which are applying in low-noise amplifiers of the radio-receiving devices of an optical and infrared range on astronomical satellites, radio telescopes and space observatories. The presented results can be used to simulate the temperature modes of MOSFET amplifiers in SPICE-type electronic simulators. The solution of this problem will predict uptime device when the temperature changes in the cases of emergency or extraordinary situations and also will allow optimizing the choice of refrigerant and increasing the reliability of the amplifier in the conditions of cryogenic temperatures.
Keywords: MOSFET, MOSFET parameters, cryogenic temperature, parameters measurement, temperature dependencies