Ceramic materials based on solid solutions La2-xSrxMO4, where M is Ni, Fe, Co, Cu, x = 0, 2 with layered K2NiF4 structure (structure of Ruddlesden-Popper) have been synthesized and investigated. The correlation of dielectric properties with a normalized bond lengths of the metal-oxygen has been observed. The existence of nickel atoms in the 2+ oxidation state for nickelates has been shown.
Keywords: solid solutions, colossal dielectric constant, resistivity, x-ray diffraction, dielectric spectrum, XANES, low-resistivity semiconductors, the activation energy, the distortion of the coordination polyhedra, oxygen non-stoichiometry
The possibility in principle of using pulp and paper industry waste as a binder for pelletization flotation potassium chloride bases on conducted researches. Defined technical conditions of pelletization flotation potassium chloride using pulp and paper industry’s waste as binder provide product with good commercial qualities, which are yield of marketable fraction (85.71 %) and resistance of granule (29.51 N). The researches for studying conditions of baking were conducted and subsisted defects on granule surfaces. There are two kinds of defects. One of them is inner defect is represented as caverns and flaws. Another type of defects are outer defects. They are represented as crystallized structural arrangements in the form of coreless tube that has net structure and includes fiber and cubic shaped microcrystals. Granule defects form after baking them with temperature higher than 120ºC.
Keywords: flotation potassium chloride; pulp and paper wastes; adhesive; commodity characteristics of fertilizers, defects granules
The factors affecting the formation of the intellectual property in economic structures. It is shown that the most important of them are: business entity formed in an innovative atmosphere, staff training and the ownership of the methodology of inventive problem solving, formed the scientific and innovative school, the presence of structure responsible for the protection of intellectual property, participation in grants initiated by the Ministry of Education and Science of Russia (in vol. h. performed under the Resolution of the Russian Government and aimed at the integration of universities with the production), access to databases of scientific and technical information.
Keywords: intellectual property, intensification, formation, protection of patents
In this article is reviewed the nature of organic hybrid nanocomposites. Promising directions in the field of organic hybrid nanocomposite materials will be methods for the synthesis of multicomponent materials, as well as the type of "net net" and "host-guest". The fundamental problem with the chemistry and physics of nanocomposites is dependent "structure-property". Solving this problem will move from research materials to their purposeful design.
Keywords: nanocomposite sol-gel technology, synthesis, nanoparticles.
The paper provides information on the results of ordination analysis of Don basin steppes
Keywords: ordination, Don basin, steppes
The method of coding of the geometrical information is offered at the task of executive mechanisms on the basis of use of the set set of spatial primitive things and their orientation in mobile systems of co-ordinates. The method of a designation of geometrical models of mechanisms of robots is offered. One of advantages of the developed method of representation of geometrical models of kinematic chains, possibility of more exact task of a spatial configuration of manipulators by means of use of a considerable quantity of central points and various position of volume primitive things concerning a constructive plane is.
Keywords: Mechanisms of manipulators, geometrical models, virtual modelling of movements of robots
This article investigated the possibility of creating a new composite material for electrical products based on natural graphite as the main component with the addition of a plasticizer . Adding plasticizer necessary to solve technological difficulties pressing process products with a high content of natural graphite . This is due to large shear between the interphase graphite flakes . As the plasticizer used polyvinylacetate . The paper presents the technological aspects of production material and study the influence of the plasticizer on the composition, both qualitative and quantitative . Conclusions about the most appropriate ratio to the amount of graphite esmestvennogo adds plasticizer.
Keywords: Еlectrotechnical products, softener for graphite, composite material, copper-graphite composition, tokosjemny material, current collecting Box, рolyvinylacetate, modification of the surface of graphite.
In the article describes the program realization of calculation unit pneumatic measuring system. The program is implemented in the languages of IEC: CFC and ST. Algorithm written with the possibility of future use in systems that differ from described in the article. The developed algorithm allows to measure temperature directly using computing power PLC and get the result in the final form, without any changes on the part of the operator.
Keywords: pneumatics, temperature, airflow, algorithm of temperature measuring, temperature measurement, Codesys, CFC, ST
In this paper a modification of logic element DC LUT FPGA is proposed for the purpose of the acceleration of diagnostics. Simulation of proposed modification was performed in the system NI Multisim 10 by National Instruments Electronics Workbench Group. Evaluation of hardware costs is also given.
Keywords: logic element, DC LUT, FPGA, diagnosis, reliability
Simulation and method of classification of technical condition high-voltage the mekhatronics of modules of the movement, allowing by results of control of electrodigit activity and skrednekvadratichesky value of vibrospeed are presented, to refer current state of object to one of classes of diagnoses
Keywords: High-voltage mekhatronics module, fuzzy-model of classification of technical condition, electrodigital activity, vibrospeed
The research of influence of periodical signal discontinuity on spectrum form is considered in the article. The numerical modeling of the system of discontinuous signals is performed. The spectrum of the system built from time discreet sampling is analyzed. The plots of the sample correlation coefficient between spectrums of continuous and discontinues signals are shown in the article. The research is needed for the development of digital measuring system for quartz plates frequency detecting.
Keywords: amplitude signal spectrum, discontinuous signal, quartz plates
The atomic structure of bimetallic nanoparticles of Pt-Ag composition, which are the part of metal-carbon electro-catalysts PtAg/C, is studied by means of EXAFS spectroscopy using the suggested technique. These materials have been prepared by methods of consistent and simultaneous deposition of Ag and Pt atoms from aqueous ethylene glycol solutions of their salts with subsequent acid treatment. The values of the structural parameters of the near environment of platinum atoms are determined. The nature of the distribution of components in nanoparticles is established. Cluster models of nanoparticles are constructed. The fraction of Pt atoms in the working shell and its dependance on preparation methods in each case are determined.
Keywords: Metal-carbon electrocatalysts, bimetallic nanoparticles, Catalysis, Platinum, X-ray absorption spectroscopy, atomic structure
This article is devoted to description of structure of methodology of modelling of hierarchical problem-directed systems on the example of social and economic systems. In the basis of methodology the principle of a combination of the formalized methods of modelling and expert procedures is put. Modelling of hierarchical system is offered to be spent by means of multilayered fuzzy cognitive maps. Filling of the block of logical-mathematical models in structure of process of decision-making is described in detail. The offered methodology provides the development and choice of well-founded administrative decisions.
Keywords: Problem-directed system, decision making, fuzzy cognitive model, methodology
This article describes a method for producing two-component nonisocyanate insulating foams and technology of its spraying on the insulated surface. It describes the device, which, along with standard equipment, includes principally new design of components pre-mixing chamber. Constructive solutions described in the article will allow using the compositions which have different time and temperature of curing than conventional PU foams.
Keywords: Keywords: spray foams, insulating foams, nonisocyanate urethanes, pre-mixing chamber.
The article presents the results of research aimed at selection of the most suitable material, shape, size of a bearing component of the device that enhances body strength of the bus. The comparative analysis of measurement results. Based on the analysis made suggestions to improve the strength characteristics of the device.
Keywords: the bus, safety of bus construction, strength, deformation, body pillar