The solid solution of LiMn1/3Cr1/3Fe1/3O2 with the structure of α-NaFeO2 isostructural with the widely used LiCoO2 has been synthesized and investigated as a cathode material. Rated voltage of LiMn1/3Cr1/3Fe1/3O2 relative to the lithium is 4 V. The possibility of charging − discharging the material to a specific capacity of 220-250 mAh/g at currents of C/15-C/50 without phase transformations has been experimentally demonstrated.
Keywords: lithium-ion batteries, cathode materials, Delafosse, solid solution, X-ray structural analysis, electrochemical properties
The results of calculations on the stability of slope lands treated in a new way. Device intrasoil walls combined with loosened intervals allows prevent subsurface runoff water, which reduces surface erosion slopes, improves the fertility of farmland returns a highly eroded areas in turn, eliminates the wetlands at the foot of the slopes. Established that the stability of the treated soil layer on the slope ample.
Keywords: stability of sloping land, subsurface walls, soil subsurface runoff, soil erosion, wetlands, deep tillage, moisture saturation slope.
Based on the analysis of works of finnish experts shows that learning russian language with learning the finnish language as a foreign supports the development of bilingual identity and language readiness of students.
Keywords: russian, finnish, teaching.
The combination of the unique, abnormal properties shown by oxidic systems with structure of spinel on the basis of transitional elements chromites draws attention of researchers for many years. Some systems on the basis of transitional elements chromites (for example, nickel and copper chromites) have critical elements (multicritical points, lines of phase transitions of the second sort, etc.) on the phase chart. Near these elements of the phase chart materials possess unique chemical and physical properties. Therefore development methods of receiving and research of phase forming and properties in NIO-CoO-CuO-Cr2O3 system represent fundamental and practical interest for chemistry and technology of inorganic substances. In this work processes of spinel structure formation in system 0,6 NiCr2O4 – 0,2 CoCr2O4 – 0,2 CuCr2O4 from crystal chemistry positions are considered. Formation of two solid solutions on the basis of nickel (II) chromite – with structure of cubic spinel and with tetragonal distorted structure is established. The influence of cooperative Yahn-Teller effect on processes of a spinel forming and on stabilizing impact of chloride of potassium on process of education of two spinel solid solutions is suggested. Influence of a power factor of cation stabilization in knots of a crystal lattice as one of the important factor in reaction of spinel structure formation is considered.
Keywords: spinels, chromites of transitional elements, Jahn-Teller effect
Nanotechnology is a technological breakthrough in agriculture, have great potential because they allow you to combine economic efficiency and natural ingredients to solve many problems in agriculture. To achieve high efficiency in agricultural production in recent years, using new agrobionanotehnologies. Authors of this article is working on the development of environmentally safe (nano) technology treatment of seeds of different crops using multi multifunctional biologically active (nano) chips. The obtained test results allow us to conclude about the prospect of being developed (nano) technology pre-sowing treatment and training opportunities 1-2 applications for patents on new research conducted in the development of the developed concept of «non-pesticidal agricultural products.
Keywords: agrobionanotehnologies, (nano) chips, pre-sowing seed, sowing qualities
The article is devoted to the analysis of the principles of energy security of the state and the study of the influence of energy on the level of national security. Considered threats to energy security and the basic directions of its implementation. Examples of world experience in ensuring the reliability of energy systems and power supply. The principles and approaches of maintaining the energy security of the state.
Keywords: electricity, security, reliability, power supply
The article suggests technique of optimization of tree cutting and skidding process via felling-skidding machines and felling-skidding-processing machines. The realization of this technique will allow reducing of time costs and raising of machine efficiency taking into account accessibility of stand cutting, relief features and technological working conditions.
Keywords: integrated machine, cutting, tree, timber harvesting, skidding.
In persisting article is offered structure and functional composition of the programme modules of the tools of the analysis dynamic mechanical systems of the class tooth issues. In change from existing, proposed programme complex contains the extended composition of the modules. This enables, in particular, check convergence iteration computing processes, way to visualizations of the current importance of the full kinetic energy of the fluctuations of the under investigation mechanical system. The broughted composition each of block of the programme complex, with detailed description of the purpose included modules into them.
Keywords: The mechanical system, tooth issue, modeling, programme complex, dynamic of the system
Fe-doped AlN nanorods were studied by means of x-ray absorption spectroscopy above the Fe K- and L2,3- edges. Theoretical simulations of the x-ray absorption spectra show that Fe atoms mainly substitute Al. A minor fraction of Fe interstitials or Fe-Al-N ternary alloy can be identified as well. Bader’s AIM analysis predicts that neutral substitutional FeAl defect is in 2+ charge state, though Al in pure AlN is in 3+ charge state. Fe L2,3 absorption spectra and photoluminescence data indicate the coexistence of Fe2+/Fe3+ in AlN:Fe nanorods so different charge states of substitutional FeAl should co-exist.
Keywords: diversification of management, production diversification, financial and economic purposes of a diversification, technological purposes of ensuring flexibility of production
This article reviews systems of respiratory activity registration in relation to sports medicine. Attention is devoted to the use of miniature accelerometers that record the movement of the chest, as the optimal method for the diagnosis of the respiratory parameters. Other methods are based on piezo-resistive sensors, pressure and airflow sensors, and airways resistance sensors. The authors' developed device based on three-axis accelerometer is proposed. It recognizes episodes of apnea with sufficient accuracy for long-term monitoring. The algorithm of the accelerometer data processing is described. In order to minimize noise impact on the useful signal it is necessary to transform the three-dimensional cloud of accelerometer data into a flat sector. Then the relation of gravity vector deviation angle and the nominal position in time is determined. This presented device due to its ability to transmit data via Bluetooth technology, after appropriate software development for mobile phone and the receiving terminal of medical professional, will be able to organize a simple ergonomic long-term remote monitoring of respiratory activity.
Keywords: systems of respiratory activity registration, long-term remote monitoring, three-axis accelerometer
In this paper we study of the local atomic and electronic structure of nanostructured condensed material for rechargeable current sources on the basis of 15mas.%V2O5/Fe/LiF nanocomposite within charge-discharge cycle. Principle component analysis (PCA) of the series of Fe K-edge spectra collected during 1 st charge showing the concentrations of the components Fe, FeF2 and V[FeV]O4. We found the changes in the V oxidation state from the analysis of the experimental Fe K- and V K- XANES spectra. Total and partial density of states of components are presented.
Keywords: nanostructured materials for rechargeable current sources, dynamics of local atomic and electronic structures, XANES, DFT
The ability to choose the right anti-wear additives [1-6 ] allows you to create lubricants , which are thin layers have different properties than in large volumes. It is commonly assumed that the additives are functioning only in the zone boundary lubrication and are outside the scope of the hydrodynamic theory of lubrication . However, the beneficial effect of additives as indicated in many studies [1-5 ] we have in the " thin layer" of hydrodynamic lubrication .As is well known , lubrication bearings operate on different types of lubricants which are composed of base oil and additive compositions that provide the required functional properties of the oil . Additives polymers with high molecular weight oils impart viscoelastic properties . Analysis of existing studies [ 7-9] on the calculation of bearings running on a viscoelastic lubricant , shows that they do not take into account the dependence of the viscosity and shear modulus of the pressure and temperature, and mode of friction is assumed laminar. It is known [ 10 ] , high-speed bearings operating in turbulent friction , higher pressure and higher temperature, and so the development of methods for calculating the bearings running on a viscoelastic lubricant requires consideration of the above factors.In connection with the above written shall first develop the computational model of thrust bearings running on micropolar lubricant with the viscosity characteristics of the lubricant on the pressure in contrast to the existing theoretical models do not take into account these dependencies (task 1).And then consider the calculation model of extra load -bearing capacity , working on a viscoelastic lubricant for the dependence of its characteristics on the pressure (objective 2).
Keywords: thrust bearing with the abutment surface adapted, non-Newtonian lubricants
The catalytic activity of Pt/C and PtxNi/C electrocatalysts prepared by borohydride methode was studed. It was established that the specific activity of fresh prepared Pt3,7Ni/C catalyst in oxygen electroreduction reaction is higher in compare with Pt/C material. After treatment of Pt3,7Ni/C material in the hot acid nickel in the surface layers of nanoparticles was dissolved and the composition of nanoparticles was changed to Pt5,6Ni. The electrochemical surface area of the Pt5,6Ni catalyst and specific activity was slightly decreased after corrosion treatment.
Keywords: platinum electrocatalysts, corrosion stability of the nanoparticles, fuel cells, X-ray diffraction, borohydride synthesis
The problems of building the architecture and design of the database structure for the storage of the structure of the chemical compounds and their analysis using heuristic algorithms
Proposed the structure of the database that allows you to store information about the structure of chemical compounds with varying degrees of detail. This approach simplifies forming of the structural descriptors used to build models of "structure-property" based on the genetic algorithms.
Keywords: database architecture, chemicals, data mining, heuristics
Information base of textile textures and materials, with the detailed description of the software for work with base is considered. It is told about methods of creation of base of textile textures and materials and about opportunities of the represented project.
Keywords: informatsionnno base, textile industry, texture, materials, visualization, software, graphics